Allylamine

Title: Allylamine
CAS Registry Number: 107-11-9
CAS Name: 2-Propen-1-amine
Additional Names: 3-aminopropylene
Molecular Formula: C3H7N
Molecular Weight: 57.09
Percent Composition: C 63.11%, H 12.36%, N 24.53%
Line Formula: CH2=CHCH2NH2
Literature References: Manuf from allyl chloride and ammonia: Ploetz, US 2915385 (1959 to Feldmühle Papier und Zellstoffwerke). Toxicity study: C. H. Hine et al., Arch. Environ. Health 1, 34 (1960).
Properties: Liquid; burning taste; strong ammonia odor causing sneezing and tears. d2020 0.760. bp 55-58°. nD20 1.4186. Flash pt, closed cup: 10°F (-12°C). Misc with water, alc, chloroform, ether. Keep tightly closed. LD50 i.p. in mice: 49 mg/kg (Hine).
Boiling point: bp 55-58°
Flash point: Flash pt, closed cup: 10°F (-12°C)
Index of refraction: nD20 1.4186
Density: d2020 0.760
Toxicity data: LD50 i.p. in mice: 49 mg/kg (Hine)
CAUTION: A strong eye and respiratory tract irritant; intolerable at 14 ppm. See Patty's Industrial Hygiene and Toxicology vol. 2B, G. D. Clayton, F. E. Clayton, Eds. (Wiley-Interscience, New York, 3rd ed., 1981) pp 3157-3158.
Use: In the manuf of mercurial diuretics.
Allylestrenol Allylprodine Allylurea Almagate Alminoprofen

Allylamine
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Identifiers
CAS number 107-11-9 YesY
ChemSpider 13835977 YesY
UNII 48G762T011 YesY
ChEMBL CHEMBL57286 YesY
RTECS number BA5425000
Jmol-3D images Image 1
Properties
Molecular formula C3H7N
Molar mass 57.09 g mol−1
Appearance Colorless liquid
Density 0.7630 g/cm3, liquid
Melting point −88 °C; −126 °F; 185 K
Boiling point 55 to 58 °C; 131 to 136 °F; 328 to 331 K
Acidity (pKa) 9.49[1]
Hazards
R-phrases R11 R23/24/25 R51/53
S-phrases S9 S16 S24/25 S45 S61
Main hazards Lachrymatory
NFPA 704
NFPA 704.svg
3
4
0
Flash point −28 °C; −18 °F; 245 K
Autoignition temperature 374 °C; 705 °F; 647 K
Explosive limits 2-22%
LD50 106 mg/kg
Related compounds
Related amine Propylamine
Related compounds Allyl alcohol
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Except where noted otherwise, data are given for materials in their standard state (at 25 °C (77 °F), 100 kPa)
Infobox references

Allylamine is an organic compound with the formula C3H5NH2. This colorless liquid is the simplest stable unsaturated amine.